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The materials were weighed in a stoichiometric ratio and ground in a mechanically activated high-energy vibro-mill for 20 min with zirconia balls in a polyethylene jar. The vibrating mill method includes four processes: (1) material destruction; (2) formation of a new surface; (3) fine grinding; and (4) transformation into a new material with a ...

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After mechanically activated by grinding in a high energy vibro-mill for 15 min with zirconia balls in a polyethylene jar, the mixtures were calcined at 1100 °C for 12 h in air. 2.2. Characterization

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The oxide powders were milled via a McCrone vibro-mill using a common plastic container for 30 min and 1 h with zirconia balls in ethanol and dried at 120 °C for 12 h. The powder mixtures were calcined at temperatures between 500 and 1100 °C for 1 h with heating/cooling rate of 5 °C min −1 in air. After that, all calcined powders were ...

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